Atkins' Physical Chemistry¶
Atkins, P., de Paula, J., & Keeler, J. (2018). Atkins' Physical Chemistry. Oxford University Press.
Cited by¶
3 citations across 3 artifacts.
Each citation links to the sentence it supports in the citing article.
Primes¶
- Activation Energy
- A heavy object has inertia; the force required to start it moving is the activation energy for motion.
This sourceCanonical physical-chemistry treatment of reaction kinetics: activation energy is the minimum energy barrier (energy difference between reactants and the activated complex/transition state) that distinguishes the measurable work to overcome resistance from passive inertia. SUPPORTS the inertia-vs-activation-energy distinction the marker sits on. NOTE: the original annotation described a 'rate-determining step' — corrected here to match the kinetics/barrier claim actually being cited.
- A heavy object has inertia; the force required to start it moving is the activation energy for motion.
- Bottleneck
- Chemistry: The rate-limiting (rate-determining) step of a multi-step reaction mechanism fixes the overall reaction rate; speeding any other step leaves the observed rate unchanged, exactly as accelerating a non-bottleneck stage leaves throughput unchanged.
This sourceStandard physical-chemistry text: the rate-determining (rate-limiting) step of a multi-step reaction mechanism fixes the overall reaction rate, so accelerating other steps leaves the observed rate essentially unchanged.
- Chemistry: The rate-limiting (rate-determining) step of a multi-step reaction mechanism fixes the overall reaction rate; speeding any other step leaves the observed rate unchanged, exactly as accelerating a non-bottleneck stage leaves throughput unchanged.
Domain-specific¶
Verification¶
Does it exist? Not checked yet. This entry carries no identifier to resolve. It was extracted from the citation as written in the article, normalized, and deduplicated against the rest of the registry.
Does it back the claim? Not recorded. Neither this nor any other of the 3 citations of this work carries a recorded support check.
Support is checked per citation rather than per work — the same source can be cited soundly in one article and wrongly in another. Per-citation recording began recently, so a citation with no recorded check is a gap in the record rather than evidence it went unchecked.
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Links previously used in the corpus¶
Before the registry existed this work was also linked 1 other way.
Registry ID ref:0c345816ebb7 · see in the full table