Controlled/living radical polymerization: Features, developments, and perspectives

Braunecker, & Matyjaszewski. (2007). Controlled/living radical polymerization: Features, developments, and perspectives: Features, developments, and perspectives. Progress in Polymer Science.

Type

Journal article

Intellectual base

Primary research

Year

2007

DOI

10.1016/j.progpolymsci.2006.11.002

DOI registrant

Elsevier

Link

https://doi.org/10.1016/j.progpolymsci.2006.11.002

Cited by

1 citation across 1 artifact.

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Domain-specific

• Polymerization
  • In chain-growth polymerization (polyethylene, polystyrene, poly(methyl methacrylate)), an initiator opens a reactive site that propagates by sequentially adding monomers — long chains appear early while monomer is still abundant; the chain-length distribution is set by the ratio of propagation to termination rate constants; and controlled variants (RAFT, ATRP, living anionic polymerization) suppress termination to produce narrow distributions with predictable chain length

    This sourceReviews ATRP, RAFT and related controlled polymerizations as suppressing termination to give narrow, predictable chain-length distributions.

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Registry ID ref:0d60ff180a07 · see in the full table