The Fluctuation Theorem and Its Applications to Non-Equilibrium Statistical Mechanics.¶
Evans, D. J., & Evans, D. J. (2020). The Fluctuation Theorem and Its Applications to Non-Equilibrium Statistical Mechanics. Reports on Progress in Physics, 61(2), 1-40.
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Primes¶
- Thermodynamic Equilibrium
- in chemistry (chemical equilibrium with equilibrium constants and Le Chatelier's principle; acid-base, solubility, redox equilibria); in materials science (phase equilibria, alloy thermodynamics, defect concentrations at thermal equilibrium); in astrophysics (local thermodynamic equilibrium in stellar atmospheres); in geochemistry (mineral equilibria in geological systems); in biology (enzyme catalysis and equilibrium product distributions; limitations of equilibrium thinking in living systems that are inherently non-equilibrium)
This sourceReviews modern developments showing how non-equilibrium steady states and fluctuation theorems (Jarzynski, Evans-Searles) extend thermodynamic thinking beyond equilibrium; clarifies conditions under which systems cannot reach equilibrium and why.
- in chemistry (chemical equilibrium with equilibrium constants and Le Chatelier's principle; acid-base, solubility, redox equilibria); in materials science (phase equilibria, alloy thermodynamics, defect concentrations at thermal equilibrium); in astrophysics (local thermodynamic equilibrium in stellar atmospheres); in geochemistry (mineral equilibria in geological systems); in biology (enzyme catalysis and equilibrium product distributions; limitations of equilibrium thinking in living systems that are inherently non-equilibrium)
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