A Stepwise Retro-Imino-Ene as a Key Step in the Mechanism of Allene Formation via the Crabbé Acetylene Homologation

González, M., Rodríguez, R. Á., Cid, M. M., & López, C. S. (2012). A Stepwise Retro-Imino-Ene as a Key Step in the Mechanism of Allene Formation via the Crabbé Acetylene Homologation. Journal of Computational Chemistry, 1236-1239.

Type

Journal article

Intellectual base

Primary research

Year

2012

DOI

10.1002/jcc.22954

Link

https://doi.org/10.1002/jcc.22954

Cited by

1 citation across 1 artifact.

Domain-specific

• Crabbé Reaction
  • Density-functional work supports a plausible metal-assisted stepwise path involving hydrogen transfer followed by C–N scission, while an uncatalyzed route is too high in energy.

Verification

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Registry ID ref:41eee7f4e59f · see in the full table