Molecular Size Distribution in Linear Condensation Polymers 1¶
Flory. (1936). Molecular Size Distribution in Linear Condensation Polymers 1. Journal of the American Chemical Society.
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Domain-specific¶
- Polymerization
- … throughout the reaction; high average molecular weight requires very high monomer conversion (Carothers equation: degree of polymerization = 1/(1 − p) where p is fractional conversion), making the final 1% of conversion critical; and the molecular-weight distribution is broad, with a polydispersity index near 2
This sourceDerives the most-probable chain-length distribution of linear step-growth polymers, whose polydispersity index approaches 2 at high conversion.
- … throughout the reaction; high average molecular weight requires very high monomer conversion (Carothers equation: degree of polymerization = 1/(1 − p) where p is fractional conversion), making the final 1% of conversion critical; and the molecular-weight distribution is broad, with a polydispersity index near 2
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Registry ID ref:42a77b4ca715 · see in the full table