Keimbildung in übersättigten Gebilden¶
Volmer, M., & Weber, Α. (1926). Keimbildung in übersättigten Gebilden. Zeitschrift für physikalische Chemie, 119, 1926-11927.
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Primes¶
- Nucleation
- The free-energy barrier comes from the explicit competition classical nucleation theory writes down: forming a spherical cluster of radius \(r\) gains a volume free energy scaling as \(-r^3\) (the favorable bulk benefit) but pays a surface free energy scaling as \(+r^2\) (the cost of the new interface).
This sourceFoundational paper of classical nucleation theory, writing the free-energy of a cluster as the competition between a negative volume term (~ −r³) and a positive surface term (~ +r²), peaking at the critical radius r*.
- The free-energy barrier comes from the explicit competition classical nucleation theory writes down: forming a spherical cluster of radius \(r\) gains a volume free energy scaling as \(-r^3\) (the favorable bulk benefit) but pays a surface free energy scaling as \(+r^2\) (the cost of the new interface).
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