Investigation of Oiling-Out Phenomenon of Small Organic Molecules in Crystallization Processes¶
Meng, Z., Huang, Y., Cheng, S., & Wang, J. (2020). Investigation of Oiling-Out Phenomenon of Small Organic Molecules in Crystallization Processes: A Review. ChemistrySelect.
Cited by¶
1 citation across 1 artifact.
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Mechanisms¶
- Solvent–Antisolvent Shift
- Its failure mode is that, instead of the intended crystalline or clean split, a too-fast or ill-chosen shift can produce oiling out — a second liquid phase or an amorphous, impurity-laden sludge that is worse to handle than no separation at all.
This sourceDescribes oiling out in antisolvent crystallization as formation of a solute-rich liquid phase instead of direct crystallization.
- Its failure mode is that, instead of the intended crystalline or clean split, a too-fast or ill-chosen shift can produce oiling out — a second liquid phase or an amorphous, impurity-laden sludge that is worse to handle than no separation at all.
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Registry ID ref:7123c4d24870 · see in the full table