Crystallization¶
Mullin, J. W. (2001). Crystallization.
Cited by¶
3 citations across 3 artifacts.
Each citation links to the sentence it supports in the citing article.
Primes¶
- Supersaturation
- In physical chemistry, supersaturated solutions, supercooled and superheated water, and supersaturated vapour each hold a variable past its equilibrium-permitted value until a seed, a scratch, or a particle opens the path.
This sourceStandard reference on solution crystallization: supersaturation as the driving force, the metastable zone held by absent nucleation, and abrupt gap-sized crystallization once a seed opens the path (e.g., the sodium-acetate hand-warmer).
- In physical chemistry, supersaturated solutions, supercooled and superheated water, and supersaturated vapour each hold a variable past its equilibrium-permitted value until a seed, a scratch, or a particle opens the path.
Domain-specific¶
- Crystallization
- The chemical-potential difference supplies thermodynamic permission, but the nucleation barrier and attachment/transport rates determine whether and how quickly crystals actually appear.
This sourceStandard specialist treatment of phase equilibria, supersaturation, nucleation, growth, and crystallizer operation.
- The chemical-potential difference supplies thermodynamic permission, but the nucleation barrier and attachment/transport rates determine whether and how quickly crystals actually appear.
- Precipitation
- Second, nucleation initiates the solid phase: either homogeneously, when random thermal fluctuations in the supersaturated solution assemble a cluster large enough that further growth reduces free energy (classical nucleation theory predicts a critical radius above which the cluster is stable)
This sourceMullin's Crystallization, whose primary-nucleation chapter covers homogeneous nucleation and the critical nucleus radius.
Supported in partVerified against the work's full text
“16.3 Crystal growth <IA_FTS_MATCH>and</IA_FTS_MATCH> dissolution |”
- Second, nucleation initiates the solid phase: either homogeneously, when random thermal fluctuations in the supersaturated solution assemble a cluster large enough that further growth reduces free energy (classical nucleation theory predicts a critical radius above which the cluster is stable)
Verification¶
Does it exist? Confirmed. This work's DOI resolves to a registered record, which fixes its identity. That is all it fixes.
Does it back the claim? Read against the text for 1 of 3 citations: 1 supported in part. Each verdict is shown under its citation below, with what in the work backs the sentence.
Support is checked per citation rather than per work — the same source can be cited soundly in one article and wrongly in another. Per-citation recording began recently, so a citation with no recorded check is a gap in the record rather than evidence it went unchecked.
See how references were verified.
Registry ID ref:b3dbd5595f34 · see in the full table