Atlas of Electrochemical Equilibria in Aqueous Solutions¶
Pourbaix, M. (1966). Atlas of Electrochemical Equilibria in Aqueous Solutions. Pergamon Press.
Cited by¶
1 citation across 1 artifact.
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Domain-specific¶
- Passivation
- The phenomenon is strictly substrate-specific in both its occurrence and its parameters: the Cr₂O₃-rich passive film on stainless steel forms and self-heals at room temperature in air, the Al₂O₃ film on aluminum provides exceptional passive protection with different potential-pH stability, the TiO₂ film on titanium confers biocompatibility, and the SiO₂ native oxide on silicon suppresses surface recombination (gate-dielectric reliability rests instead on a deliberately grown thermal oxide, not on the air-grown native film) — each system has its own Pourbaix-diagram passivation region, its own passive-current density, and its own susceptibility to specific aggressive species
This sourceThe potential-pH equilibrium diagrams that give each metal-water system its own bounded passivation region.
- The phenomenon is strictly substrate-specific in both its occurrence and its parameters: the Cr₂O₃-rich passive film on stainless steel forms and self-heals at room temperature in air, the Al₂O₃ film on aluminum provides exceptional passive protection with different potential-pH stability, the TiO₂ film on titanium confers biocompatibility, and the SiO₂ native oxide on silicon suppresses surface recombination (gate-dielectric reliability rests instead on a deliberately grown thermal oxide, not on the air-grown native film) — each system has its own Pourbaix-diagram passivation region, its own passive-current density, and its own susceptibility to specific aggressive species
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