Ueber verschiedene für die Anwendung bequeme Formen der Hauptgleichungen der mechanischen Wärmetheorie.¶
Clausius, R. (1865). Ueber verschiedene für die Anwendung bequeme Formen der Hauptgleichungen der mechanischen Wärmetheorie. Annalen der Physik und Chemie, 125(7), 353-400.
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2 citations across 2 artifacts.
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Primes¶
- Dissipation
- Dissipation is the systematic, irreversible transformation of organized energy or structural order into a thermalized, un-recoverable form through interactions with many degrees of freedom, a process whose modern thermodynamic formulation traces to Clausius (1865) and the introduction of entropy as a state function bookkeeping the universal one-way tendency.
This sourceIntroduces the term "entropy" and gives the modern statement of the second law (the entropy of the universe tends to a maximum); establishes entropy as a state function that bookkeeps the universal one-way tendency now grouped under dissipation.
- Dissipation is the systematic, irreversible transformation of organized energy or structural order into a thermalized, un-recoverable form through interactions with many degrees of freedom, a process whose modern thermodynamic formulation traces to Clausius (1865) and the introduction of entropy as a state function bookkeeping the universal one-way tendency.
- Entropy (Thermodynamic Sense)
- … choice of statistical ensemble — microcanonical (fixed energy, S = k_B ln Ω), canonical (fixed temperature, S = −k_B Σ p_i ln p_i in the Gibbs form), grand canonical — with appropriate entropy formula; (3) the relation to heat and temperature — dS ≥ δQ/T with equality for reversible processes (Clausius's definition
This sourceCoins the term 'entropy' and states the modern second law ('the entropy of the universe tends to a maximum'); establishes entropy as a state function with dS = δQ_rev/T.
- … choice of statistical ensemble — microcanonical (fixed energy, S = k_B ln Ω), canonical (fixed temperature, S = −k_B Σ p_i ln p_i in the Gibbs form), grand canonical — with appropriate entropy formula; (3) the relation to heat and temperature — dS ≥ δQ/T with equality for reversible processes (Clausius's definition
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