Synthesis and (spectro)electrochemistry of mixed-valent diferrocenyl–dihydrothiopyran derivatives¶
Kowalski. (2015). Synthesis and (spectro)electrochemistry of mixed-valent diferrocenyl–dihydrothiopyran derivatives. Dalton Transactions, 6268-6276.
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Domain-specific¶
- Weakly coupled class-II mixed-valence state of a dinuclear complex
- Weak, nonzero electronic interaction between the sites and a source-supported class-II interpretation describe a state that is partly localized in the Robin–Day scheme.
This sourceX-ray characterization is of neutral 1; 1+ was generated in situ. The IVCT band is weak and the proposed through-space predominance is qualified.
- Weak, nonzero electronic interaction between the sites and a source-supported class-II interpretation describe a state that is partly localized in the Robin–Day scheme.
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