Polar and Steric Substituent Constants for Aliphatic and o-Benzoate Groups from Rates of Esterification and Hydrolysis of Esters

Taft, R. W. (1952). Polar and Steric Substituent Constants for Aliphatic and o-Benzoate Groups from Rates of Esterification and Hydrolysis of Esters. Journal of the American Chemical Society, 3120-3128.

Type

Journal article

Intellectual base

Primary research

Year

1952

DOI

10.1021/ja01132a049

Link

https://doi.org/10.1021/ja01132a049

Cited by

1 citation across 1 artifact.

Domain-specific

• Taft Equation
  • Taft's 1952 work derived polar and steric substituent constants for aliphatic and ortho-benzoate groups from ester reactions, establishing the paired-descriptor framework.

Verification

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Registry ID ref:d2b3e9522251 · see in the full table