March's Advanced Organic Chemistry¶
Smith, M. B. (2013). March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure. Wiley.
Cited by¶
1 citation across 1 artifact.
Each citation links to the sentence it supports in the citing article.
Domain-specific¶
- Side Reaction
- The two carry different activation parameters — elimination, which breaks more bonds in the transition state and increases the particle count, has the higher activation energy and larger entropy of activation
This sourceThe standard reference for the substitution-versus-elimination competition; the specific activation-parameter asymmetry was not checkable against the text here. The standard reference for the temperature and nucleophile-bulk rules governing substitution versus elimination; the passage itself was not reachable for checking here.
- The two carry different activation parameters — elimination, which breaks more bonds in the transition state and increases the particle count, has the higher activation energy and larger entropy of activation
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