Nucleation in Condensed Matter¶
Kelton, K. F., & Greer, A. L. (2010). Nucleation in Condensed Matter: Applications in Materials and Biology.
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Primes¶
- Supersaturation
- What keeps it there is kinetic isolation — crystallization requires a nucleus to form, and forming one from a clean solution must surmount the surface-energy barrier of the classical nucleation rate $J \propto \exp(-\Delta G^\/k_BT)$ with $\Delta G^\ \propto \gamma^3/\Delta\mu^2$;
This sourceAuthoritative treatment of classical nucleation theory, including the barrier ΔG ∝ γ³/Δμ² and rate J ∝ exp(−ΔG/kBT) that holds a supersaturated state kinetically isolated.
- What keeps it there is kinetic isolation — crystallization requires a nucleus to form, and forming one from a clean solution must surmount the surface-energy barrier of the classical nucleation rate $J \propto \exp(-\Delta G^\/k_BT)$ with $\Delta G^\ \propto \gamma^3/\Delta\mu^2$;
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