THE ADSORPTION OF GASES ON PLANE SURFACES OF GLASS, MICA AND PLATINUM¶
Langmuir, I. (1918). THE ADSORPTION OF GASES ON PLANE SURFACES OF GLASS, MICA AND PLATINUM. Journal of the American Chemical Society.
Cited by¶
2 citations across 2 artifacts.
Each citation links to the sentence it supports in the citing article.
Domain-specific¶
- Adsorption
- The Langmuir isotherm — derived by assuming identical, independent binding sites — captures the saturation behavior as a rectangular hyperbola: surface coverage θ = (KC)/(1 + KC), where K is an affinity constant and C is bulk concentration, so coverage rises steeply at low bulk concentrations and flattens at a monolayer maximum
Supported in partVerified against the source
- The Langmuir isotherm — derived by assuming identical, independent binding sites — captures the saturation behavior as a rectangular hyperbola: surface coverage θ = (KC)/(1 + KC), where K is an affinity constant and C is bulk concentration, so coverage rises steeply at low bulk concentrations and flattens at a monolayer maximum
- Adsorption Isotherm
- A Langmuir isotherm — the canonical case for a surface with uniform, non-interacting sites — rises linearly at low concentration (Henry's law regime)
This sourceThe original derivation of the uniform-site monolayer isotherm and its low-coverage linear limit. Langmuir's own statement of the equivalent-site, one-molecule-per-site, dynamic-balance assumptions.
- A Langmuir isotherm — the canonical case for a surface with uniform, non-interacting sites — rises linearly at low concentration (Henry's law regime)
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