The theory of Ostwald ripening¶
Voorhees. (1985). The theory of Ostwald ripening. Journal of Statistical Physics.
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1 citation across 1 artifact.
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Domain-specific¶
- Ostwald Ripening
- The mechanism runs on a thermodynamic driver — reduction of total interfacial free energy, which is lower in one large particle than in many small ones of equal total volume — expressed as a kinetic process limited by mass transport through the matrix: diffusion-limited ripening produces mean-radius growth scaling as t^(⅓) while interface-limited ripening scales as t^(½), both with a self-similar normalized size distribution that converges asymptotically to the Lifshitz-Slyozov-Wagner (LSW) form
This sourceA review of post-Lifshitz–Slyozov Ostwald-ripening theory, covering the asymptotic state first discovered by LS and the way it is approached, finite-volume-fraction effects, transients and the role of elastic fields. The bounds on the Lifshitz–Slyozov asymptotic coarsening state - finite volume fraction of the coarsening phase, transient ripening, and the approach to the asymptotic distribution.
Supported in partVerified against the work's full text
“Developments in the theory of Ostwald ripening since the classic work of I. M. Lifshitz and V. V. Slyozov (LS) are reviewed and directions for future work are suggested.”
- The mechanism runs on a thermodynamic driver — reduction of total interfacial free energy, which is lower in one large particle than in many small ones of equal total volume — expressed as a kinetic process limited by mass transport through the matrix: diffusion-limited ripening produces mean-radius growth scaling as t^(⅓) while interface-limited ripening scales as t^(½), both with a self-similar normalized size distribution that converges asymptotically to the Lifshitz-Slyozov-Wagner (LSW) form
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