Atkins' Physical Chemistry¶
Atkins, P., & de Paula, J. (2014). Atkins' Physical Chemistry. Oxford University Press.
Cited by¶
5 citations across 5 artifacts.
Each citation links to the sentence it supports in the citing article.
Primes¶
- Catalysis
- Chemistry and biology (origin substrate): enzymes, transition-metal and acid/base catalysts, zeolites; ribozymes extend the pattern to nucleic acids, and catalytic selectivity is the basis of metabolic specificity.
This sourceStandard treatment of catalysis: catalysts lower activation energy on a specific pathway without being consumed and without shifting equilibrium; homogeneous vs. heterogeneous, enzymes, and poisoning.
- Chemistry and biology (origin substrate): enzymes, transition-metal and acid/base catalysts, zeolites; ribozymes extend the pattern to nucleic acids, and catalytic selectivity is the basis of metabolic specificity.
- Micro Macro Linkage
- The across-macro edge is the dynamics over time, e.g. the ideal gas law \(PV = nRT\) governing how the macro variables co-move.
This sourceStandard physical-chemistry text stating the ideal (perfect) gas law PV = nRT, the across-macro thermodynamic relation governing how the bulk gas variables co-move.
- The across-macro edge is the dynamics over time, e.g. the ideal gas law \(PV = nRT\) governing how the macro variables co-move.
- Preparation
- Not activation energy. `activation_energy` is the threshold barrier itself — the cost to cross from idle to active.
This sourceDefines activation energy as the threshold barrier that must be surmounted for a process to proceed from reactants to products.
- Not activation energy. `activation_energy` is the threshold barrier itself — the cost to cross from idle to active.
Domain-specific¶
- Isolated System
- In standard thermodynamic usage, a closed system exchanges no matter but may exchange energy as heat or work
SupportedVerified against the source
- In standard thermodynamic usage, a closed system exchanges no matter but may exchange energy as heat or work
- Solubility
- The equilibrium is characterized by the solubility product Ksp for sparingly soluble ionic compounds (Ksp = [A⁺]n for the solid A_mB_n in equilibrium with its ions, with Ksp exponentially sensitive to temperature) and by the partition coefficient log P for molecular solutes distributed between immiscible phases
This sourceAtkins' Physical Chemistry, which works the solubility product of sparingly soluble compounds against their solubility and treats the temperature coefficient of solubility among its equilibrium constants.
Supported in partVerified against the work's full text
“expression for I— ^ the temperature [coefficient] of the [solubility], dxB/dT, and plot it as a function”
- The equilibrium is characterized by the solubility product Ksp for sparingly soluble ionic compounds (Ksp = [A⁺]n for the solid A_mB_n in equilibrium with its ions, with Ksp exponentially sensitive to temperature) and by the partition coefficient log P for molecular solutes distributed between immiscible phases
Verification¶
Does it exist? Confirmed. This work's ISBN resolves to a registered record, which fixes its identity. That is all it fixes.
Does it back the claim? Read against the text for 2 of 5 citations: 1 supported, 1 supported in part. Each verdict is shown under its citation below, with what in the work backs the sentence.
Support is checked per citation rather than per work — the same source can be cited soundly in one article and wrongly in another. Per-citation recording began recently, so a citation with no recorded check is a gap in the record rather than evidence it went unchecked.
See how references were verified.
Registry ID ref:fb26efc21036 · see in the full table